NTL Record

Title Comparison of Species-Specific β-Glucuronidase Hydrolysis of Cannabinoid Metabolites in Human Urine
Record ID 81841
Personal Name
Creator
Kemp, Philip M.; Cliburn, Kacey D
Corporate Creator United States. Department of Transportation. Federal Aviation Administration. Office of Aviation. Civil Aerospace Medical Institute
Corporate
Contributor
United States. Department of Transportation. Federal Aviation Administration. Office of Aviation. Office of Aerospace Medicine
Publisher United States. Department of Transportation. Federal Aviation Administration. Office of Aviation. Civil Aerospace Medical Institute
Publication Date 20150301
Language English
Abstract Toxicological investigations of fatal aviation accidents include testing for ∆9 -tetrahydrocannabinol (THC), the active component of marijuana, and its major metabolite, 11-nor-9-carboxy-∆9 -THC (THCCOOH) in postmortem fluids and tissues from deceased pilots. These cannabinoids, as well as others, exist in human urine as their glucuronide conjugates, formed during Phase II metabolism to increase their solubility for excretion. Prior to the analysis of cannabinoids in urine by gas chromatography/mass spectrometry (GC-MS), it is desirable to cleave (hydrolyze) the glucuronic acid to enhance the detection of the unconjugated compounds. In the current study, β-glucuronidases from 3 mollusk species (Helix pomatia, Patella vulgate, and Haliotis rufescens), 1 bacteria (Escherichia coli), and bovine liver were compared for their quantitative efficiency in hydrolyzing the glucuronide bond in spiked, blank urine.
Rosap ID dot:57190
Rosap URL https://rosap.ntl.bts.gov/view/dot/57190
TRT Terms Animals; Gas chromatography; Hydrolysis; Marijuana; Mass spectrometry; Toxicology; Urine; Forensic science; Aviation
General Subjects Glucuronidase; Cannabinoids; Tetrahydrocannabinol
Geographical
Coverage
United States
TRIS Online
Accession No
1563640
Report Number DOT/FAA/AM-15/6
Resource type Tech Report
URL https://ntlrepository.blob.core.windows.net/lib/81000/81800/81841/201506.pdf
Format PDF
Database NTL Digital Repository